Budgets of Mn,Cd and Cu in the macrotidal Gironde estuary (SW France)     

Stéphane Audry  Gérard BlancJörg Schäfer  Frédéric GuérinMatthieu Masson  Sébastien Robert 《Marine Chemistry》2007

The behavior and budget of Mn, Cd and Cu in the Gironde estuary were investigated through data from both the water column (WC) and sediment depth profiles. In the estuarine freshwater reaches, Mn and Cd removal from and Cu addition to the dissolved phase occurs with a magnitude equivalent to 10%, 30% and 25% of their respective annual fluvial gross dissolved input, respectively. In the saline estuary, diffusive benthic outflow is the main source of dissolved Mn (74% of the total gross dissolved input within the estuary) to the WC. In contrast, Cd (96%) and Cu (89%) are mainly released into the dissolved phase of the WC from fluvial, estuarine and dredging-related particles through complexation (Cd) and organic carbon mineralization (Cu). Anthropogenic activities (sediment dredging) induce pore water inputs, particulate sulfide oxidation and sediment resuspension, significantly contributing to the metal budget of the WC. The related amounts of metals released could be equivalent to 20–50% (Cd) and up to 70% (Cu) of their respective net dissolved addition. Mass balances suggest that a large part of the metals previously released into the dissolved phase from processes within the estuary are removed by suspended particles due to (co-)precipitation of Fe/Mn (oxy)hydroxides and scavenging on autochthonous organic matter. On an annual basis, the Gironde estuary acts as a net sink of dissolved Mn, removing 60% of the dissolved fluvial inputs, and as a net source of dissolved Cd and Cu, contributing ∼ 85% and 20–45% to the dissolved Cd and Cu fluxes to the ocean.  相似文献   

The European coastal zone: characterization and first assessment of ecosystem metabolism     

Frdric Gazeau  Stephen V. Smith  Bernard Gentili  Michel Frankignoulle  Jean-Pierre Gattuso 《Estuarine, Coastal and Shelf Science》2004,60(4):673-694

The geomorphic, oceanographic, terrestrial and anthropogenic attributes of the European coastal zone are described and published data on ecosystem function (primary production and respiration) are reviewed. Four regions are considered: the Baltic Sea, Mediterranean Sea, Black Sea and the European Atlantic coast including the North Sea. The metabolic database (194 papers) suffers from a non-homogeneous geographical coverage with no usable data for the Black Sea which was therefore excluded from this part of our study. Pelagic gross primary production in European open shelves is, by far, the most documented parameter with an estimated mean of 41 mmol C m⁻² d⁻¹, the lowest value is reported in the Mediterranean Sea (21 mmol C m⁻² d⁻¹) and the highest one in the Atlantic/North Sea area (51 mmol C m⁻² d⁻¹). Microphytobenthic primary production, mostly measured in shallow areas, is extrapolated to the entire 0–200 m depth range. Its contribution to total primary production is low in all regions (mean: 1.5 mmol C m⁻² d⁻¹). Although macrophyte beds are very productive, a regional production estimate is not provided in this study because their geographical distribution along the European coastline remains unknown. Measurements of pelagic community respiration are clearly too sparse, especially below the euphotic zone, to yield an accurate picture of the fate of organic matter produced in the water column. With a mean value of 17 mmol C m⁻² d⁻¹, benthic community respiration consumes approximately 40% of the pelagic organic matter production. Estuaries generally exhibit high metabolic rates and a large range of variation in all parameters, except microphytobenthic primary production. Finally, the problem of eutrophication in Europe is discussed and the metabolic data obtained in the framework of the Land–Ocean Interactions in the Coastal Zone (LOICZ) project are compared with available direct measurements of net ecosystem production.  相似文献   

Type III radio burst productivity of solar flares     

M. PoquÉrusse  P. S. McIntosh 《Solar physics》1995,159(2):301-323

We study the occurrence probability of type III radio bursts during flares as a function of the flare position on the Sun. We find that this probability peaks around 30° east of the central meridian, which points to a reciprocal tilt of the average radiation pattern of type IIIs. We argue that anisotropic scattering of the radiation by overdense coronal fibers parallel to the magnetic field is the dominant factor determining the orientation of radiation patterns. It follows that the average magnetic field appears to be tilted 30° west from the vertical. We also find that within a given active region, the average type III production rate of flares peaks 1° west of the center of gravity of all the flares of this active region.We infer that the coronal magnetic field above active regions presents a strong east-west asymmetry, resulting from the well known asymmetry at the photospheric level. As the west side of an active region covers a smaller area with stronger magnetic field than the east side, western flares are generally closer to open field lines than eastern flares. As a consequence, accelerated particles on the trailing (east) side of active regions usually stay trapped in magnetic loops, while on the leading (west) side they are more likely to escape along open lines into interplanetary space. As a result of the initial westward tilt of these open lines, we estimate that the corresponding Archimedean spiral is on average (apparently) rooted 15° west of the flare.  相似文献   

Airborne gamma-ray spectrometry to quantify chemical erosion processes     

F. Carrier  B. Bourdon  . Pili  C. Truffert  R. Wyns 《Journal of Geochemical Exploration》2006,88(1-3):266

Airborne gamma-ray spectrometry data (uranium, potassium and thorium contents) reveal geochemical heterogeneities within the monolithological Hyrôme watershed (ca. 150 km²) in the Armorican massif (western France). Our observations and computations provide important constraints on the spatial distribution and the associated magnitudes of chemical erosion processes at the scale of a small watershed. Two distinct, partially preserved, weathering profiles exhibit a strong correlation between regolith evolution and airborne-derived K/Th ratios, suggesting that the variability is linked to supergene processes. Using both airborne data and laboratory measurements on rock samples, the total net export of potassium has been estimated at 422 ± 50 kg/m² and the chemical weathering rate of potassium at 17 ± 2 kg/km²/a.  相似文献   

Computation of Large Anisotropic Seismic Heterogeneities (CLASH)     

Éric Beucler  Jean-Paul Montagner 《Geophysical Journal International》2006,165(2):447-468

A general tomographic technique is designed in order (i) to operate in anisotropic media; (ii) to account for the uneven seismic sampling and (iii) to handle massive data sets in a reasonable computing time. One modus operandi to compute a 3-D body wave velocity model relies on surface wave phase velocity measurements. An intermediate step, shared by other approaches, consists in translating, for each period of a given mode branch, the phase velocities integrated along ray paths into local velocity perturbations. To this end, we develop a method, which accounts for the azimuthal anisotropy in its comprehensive form. The weakly non-linear forward problem allows to use a conjugate gradient optimization. The Earth's surface is regularly discretized and the partial derivatives are assigned to the individual grid points. Possible lack of lateral resolution, due to the inescapable uneven ray path coverage, is taken into account through the a priori covariances on parameters with laterally variable correlation lengths. This method allows to efficiently separate the 2ψ and the 4ψ anisotropic effects from the isotropic perturbations. Fundamental mode and overtone phase velocity maps, derived with real Rayleigh wave data sets, are presented and compared with previous maps. The isotropic models concur well with the results of Trampert & Woodhouse. Large 4ψ heterogeneities are located in the tectonically active regions and over the continental lithospheres such as North America, Antarctica or Australia. At various periods, a significant 4ψ signature is correlated with the Hawaii hotspot track. Finally, concurring with the conclusions of Trampert & Woodhouse, our phase velocity maps show that Rayleigh wave data sets do need both 2ψ and 4ψ anisotropic terms.  相似文献   

Design of Inclined Covers with Capillary Barrier Effect     

Serge-Étienne Parent  Alexandre Cabral 《Geotechnical and Geological Engineering》2006,24(3):689-710

A design procedure is proposed to minimize water infiltration into landfills by optimizing the water diversion length of inclined covers with capillary barrier effect (CCBE). This design procedure is based on a conceptual, mathematical and numerical approach and aims at selecting materials and optimizing layer thickness. Selection among candidate materials is made based on their hydraulic conductivity functions and on a threshold infiltration rate imposed on the designer. The capillary break layer (CBL; bottom layer) is characterized by a weak capillarity, while the moisture retention layer (MRL; upper layer) is characterized by a compromise between strong capillarity and high hydraulic conductivity. The thickness of the CBL corresponds to the height where suction reaches its maximum value for a given infiltration rate. This height can be calculated using the Kisch [Géotechnique 9 (1959)] model. The optimal thickness of the MRL is determined by applying an adaptation of the Ross [Water Resources Research 26 (1990)] model. The results obtained using the proposed design procedure were compared to those obtained from numerical simulations performed using a finite element unsaturated seepage software. The procedure was applied for two cover systems; one where deinking by-products (DBP) were used as MRL and sand as CBL and another where sand was used as MRL and gravel as CBL. Using this procedure, it has been shown that an infiltration control system composed of thin layers of sand over gravel is highly efficient in terms of diversion length and that its efficiency can be enhanced by placing a hydraulic barrier – such as a layer of DBP – above the MRL.  相似文献   

Contested terrains: Cities and hinterlands in post-apartheid boundary delimitations   总被引：1，自引：0，他引：1  

Frédéric Giraut  Brij Maharaj 《GeoJournal》2002,57(1-2):39-51

In South Africa attempts are being made to address the socio-spatial distortions of the apartheid era through a more equitable distribution of resources, and the re-drawing of municipal geographical boundaries. However, boundaries are not neutral geographic lines. Boundary changes are often associated with a redistribution of political power and resources. The aim of this paper is to analyse the effects of the contemporary territorial and administrative restructuring on urban dynamics in South Africa. More specifically, the focus is on how the process of territorial restructuring impacted on metropolitan areas as well as on secondary cities and their hinterlands. Examining and elucidating the manner in which various social, economic and political forces have manifested themselves in the process of boundary delimitation in a major metropolitan centre as well as adjacent rural areas is a central theme of this paper. There were considerable contestations over the delimitation of new local government boundaries. Affluent metro authorities like that in Durban were opposed to the spatial extension of their boundaries because of the costs of the providing services and infrastructure in the deprived margins. Similarly, there was concern that incorporation of rural areas will result in increased municipal service charges being imposed on these communities. Tensions were heightened between urban and rural regions because traditional leaders believed that their territorial jurisdiction and authority were being undermined. In other parts of the country, the merger of traditionally white and black fragments of secondary cities often resulted in many black locations continuing to be marginalized. There appears to be neither the political will nor the economic capacity to upgrade these zones of marginalized urban communities. While the Municipal Demarcation Board was largely successful in eliminating the political geography of apartheid at a macro- scale, this paper suggests that the greater challenge for government and policy makers is to reduce the socio-spatial and economic inequalities which appears to be still very high and perhaps increasing. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Seismic endoscopy: multi-offset multi-azimuth imaging around boreholes – data processing and experimental results     

Florence Nicollin  Frédéric Conil  Dominique Gibert 《Geophysical Prospecting》2002,50(5):475-485

An acoustic method, called seismic endoscopy, able to perform 3D imaging around shallow-depth boreholes is presented. A probe, composed of an isotropic source and a directional receiver working in the 20–100 kHz frequency range, provides images of cylindrical volumes having radii of a few metres, with an accuracy of centimetres and 25° azimuthal directivity. In order to obtain clear images of the medium discontinuities, multi-offset and multi-azimuth data acquisition allows specific algorithms to be used to determine vertical directivity correction, azimuthal focusing and reflected wave enhancement by cancellation of the tube waves. The method is tested with data acquired in an acoustic tank and with synthetic data. Initial experimental results at a test site demonstrate the performance of the seismic endoscopy probe.  相似文献   

Lateglacial palaeoenvironments and palaeoclimates from Conty and Houdancourt, northern France, reconstructed from Beetle remains     

Philippe Ponel  Russell Coope  Pierre Antoine  Nicole Limondin-Lozouet  Chantal Leroyer  Andr-Valentin Munaut  Jean-Franois Pastre  Frdric Guiter 《Quaternary Science Reviews》2005,24(23-24):2449-2465

Two Lateglacial insect sequences are described (a) from Conty, in the Selle valley and (b) from Houdancourt in the Oise valley, both in northern France. These investigations are part of a multidisciplinary investigation involving archaeology, sedimentology, geomorphology, geochronology and palaeontology (pollen, macroscopic plant remains, vertebrates, molluscs and insect fossils). The sequences of insect assemblages date from the latter part of the Bølling to the end of the Allerød periods. Environmental analysis of these faunas shows that rivers with riffles and pools meandered across flood plains. The river was extensively fringed with reedy vegetation. The only trees growing close to the river were of Salix and/or Populus. All the insect assemblages indicate that the thermal climates during the Bølling and Allerød periods were similar to one another and during both periods were very nearly as warm as that of the present day. No insect fossils were recovered from the sediments attributed to the Older Dryas interval though other evidence from these sites suggests that this event was decidedly colder than those immediately preceding and succeeding it. Comparisons are made between Lateglacial climatic patterns in northern France with those elsewhere in Europe.  相似文献   

Empirical determination of diffusion coefficients and geospeedometry     

Olivier Jaoul  Frédéric Béjina 《Geochimica et cosmochimica acta》2005,69(4):1027-1040

Geospeedometry allows to estimate the cooling rate (s_init) of metamorphic rocks at the beginning of the cooling history using diffusion data. But the choice of a diffusion activation energy (E) and a preexponential factor (D₀) from experimental results can be difficult. We propose a method to obtain E directly from the rock itself by studying the variation of the average concentration of elements or isotopes (〈C〉) as a function of mineral grain size (d). An appropriate value of D₀ can then be estimated using an existing compensation rule, a linear relationship between log D₀ and E. Consequently, uncertainties on s_init are markedly reduced. All parameters of this analytical model and their sensitivity on s_init can be estimated from 〈C〉 of the mineral grains under study. As a test we apply our model to a study by Edwards and Valley (1998)**** on ¹⁸O/¹⁶O fractionation between diopside and calcite in Adirondacks marbles, and find a cooling rate in agreement with previous works, without choosing experimental values for E and D₀.  相似文献